87. Wang, Y.; Huang, Z.; Liu, G.; Huang, Z.* “A New Paradigm in Pincer Iridium Chemistry: PCN complexes for (De)Hydrogenation Catalysis and Beyond” Acc. Chem. Res. 2022, 55, 2148.

86. Wang, K.;# Gan, L.; # Wu, Y.; Zhou, M. Liu, G.; Huang, Z.* “Selective Dehydrogenation of Small and Large Molecules by a Chloroiridium Catalyst” Sci. Adv. 2022, 8, eabo6586 (#contributed equally)

85. Huang, F.; Huang, Z.; Liu, G.*; Huang, Z.* “Iridium-Catalyzed Selective tran-Semihydrogenation of 1,3-enynes with Ethanol: Access to (E,E)-1,4-Diarylbutadienes” Org. Lett. 2022, 24, 5486.

84. Su, Y.; Yu, F.; Liu, G.*; Huang, Z.* “Dehydrogenation Based Asymmetric Epoxidation of Arylalkanes to Chiral Epoxides” Chin. J. Chem. 2022.

83. Yu, F.; Tao, R.; Su, Y.; Liu, G.*; Huang, Z.* “Undirected, Asymmetric Alkyl Group Functionalizations through Alkane Dehydrogenation” Org. Lett. 2022, 24, 4563.

82. Qian, L.; Tang, X.; Wang, Y.; Liu, G.*; Huang, Z.* “Asymmetric Transfer Hydrogenation of Diaryl Ketones with Ethanol Catalyzed by Chiral NCP Pincer Iridium Complexes” Chin. J. Chem. 2022, 40, 1131-1136.

81. Qian, L.; Tang, X.; Huang, Z.; Wang, Y.; Liu, G.*; Huang, Z.* “Chiral Iridium Complexes of Anionic NCP Pincer Ligand for Asymmetric Transfer Hydrogenation of 1,1-Diarylethenes with Ethanol” Org. Lett. 2021, 23, 8978-8983.

80. Zhou, M.-J.; Zhang, L.; Liu, G.; Xu, C.*; Huang, Z.* “Site-Selective Acceptorless Dehydrogenation of Aliphatics Enabled by Organophotoredox/Cobalt Dual Catalysis” J. Am. Chem. Soc. 2021, 143, 16470-16485.

79. Wang, Z.; Fang, H.; Liu, G.*; Huang, Z.* “Ruthenium-Catalyzed Dual Dehydrogenative Silylation of C(sp3)-H Bonds: Access to Diverse Silicon-Centered Spirocycles” Org. Lett. 2021, 23, 7603-760.

78. Zhang, X.; Geng, P.; Liu, G.*; Huang, Z.* “Ru-Catalyzed Site-Selective Aliphatic C-H Bond Silylation of Amides and Carbamides” Organometallics 2021, 40, 2365-2370.

77. Xu, S.; Geng, P.; Li, Y.; Liu, G.; Zhang, L.; Guo, Y.*; Huang, Z.* “Pincer Iron Hydride Complexes for Alkene Isomerization: Catalytic Approach to Trisubstituted (Z)-Alkenyl Boronates” ACS Catal. 2021, 11, 10138-10147.

76. Huang, Z.;# Wang, Y.; # Leng, X.; Huang, Z.* “An Amine-Assisted Ionic Monohydride Mechanism Enables Selective Alkyne Cis-Semihydrogenation with Ethanol: from Elementary Steps to Catalysis” J. Am. Chem. Soc. 2021, 143, 4824-4836. (#contributed equally)

75. Guo, Z.; Wen, H.; Liu, G.*; Huang, Z.* “Iron-Catalyzed Regio- and Stereoselective Hydrosilylation of 1,3- Enynes To Access 1,3-Dienylsilanes” Org. Lett. 2021, 23, 2375-2379.

74. Xu, S.; Liu, G.*; Huang, Z.* “Iron Catalyzed Isomerization of ?-Alkyl Styrenes to Access Trisubstituted Alkenes” Chin. J. Chem. 2021, 39, 585-589.

73. Fang, H.; He, Q; Liu, G.; Huang, Z.* “Ruthenium-Catalyzed Hydrodefluorination with Silane as the Directing and Reducing Group” Org. Lett. 2020, 22, 9298-9302.

72. Li, C.; Yang, Z.; Wang, L.; Guo, Y.*; Huang, Z.*; Ma, S. “Cobalt-Catalyzed Regio- and Stereoselective Hydroboration of Allenes” Angew. Chem. Int. Ed. 2020, 59, 6278–6283.

71. Hou, W.; Zhang, D.; Camacho-Fernandez, M. A.; Zhang, Y.; Liu, G.*; Tang, Y.; Guan, Z.*; Huang, Z.* “Double-Linear Insertion Mode of ?,?-Dienes Enabled by Thio-iminoquinoline Iron Catalyst” ACS Catal. 2020, 10, 15092-15103.

70. Tang, X.; Gan, L.; Zhang, X.; Huang, Z.* “n-Alkanes to n-Alcohols: Formal Primary C-H Bond Hydroxymethylation via Quadruple Relay Catalysis” Sci. Adv. 2020, 6, eabc6688.

69. He, Q.; Huang, Z.* “Single-Step Construction of Carbon Chirality and Axial Chirality by Enantioselective Hydrosilylation of Maleimides” Chin. J. Org. Chem. 2020, 40, 3478-3480.

68. Gan, L.; Jia, X.; Fang, H.; Liu, G.*; Huang, Z.* “Dehydrogenation of Primary Alkyl Azides to Nitriles Catalyzed by Pincer Iridium/Ruthenium Complexes” ChemCatChem 2020, 12, 3661-3665.

67. Liu, G.*; Huang, Z.* “Recent Advances in Coordination-Insertion Copolymerization of Ethylene with Polar Functionalized Comonomers” Chin. J. Chem. 2020, 38, 1445-1448.

66. Wang, Y.; Qian, L.; Huang, Z.; Liu, G.*; Huang, Z.* “NCP-Type Pincer Iridium Complexes Catalyzed Transfer-Dehydrogenation of Alkanes and Heterocycles” Chin. J. Chem. 2020, 38, 837-841.

65. Zhang, X.; Wu, S.; Leng, X; Chung, L. W.; Liu, G.; Huang, Z.* “N-Bridged Pincer Iridium Complexes for Highly Efficient Alkane Dehydrogenation and the Relevant Linker Effects” ACS Catal. 2020, 10, 6475-6487.

64. Qiao, L.; Zhang, L.; Liu, G.*; Huang, Z.* “A Highly Efficient Cobalt-Catalyzed Deuterogenolysis of Diboron: Synthesis of Deuterated Pinacolborane and Vinylboronates” Tetrahedron 2019, 75, 4138-4142.

63. Wang, Y.; # Huang, Z.; # Huang, Z.* “Catalyst as colour indicator for endpoint detection to enable selective alkyne trans-hydrogenation with ethanol” Nat. Catal. 2019, 2, 529-536. (#contributed equally)

62. Zuo, Z.; Xu, S.; Zhang, L.; Gan, L.; Fang, H.; Liu, G.*; Huang, Z.* “Cobalt-Catalyzed Asymmetric Hydrogenation of Vinylsilanes with a Phosphine-Pyridine-Oxazoline Ligand: Synthesis of Optically Active Organosilanes and Silacycles” Organometallics 2019, 38, 3906-3911

61. Peng, S.; Yang, J.; Liu, G.*; Huang, Z.* “Ligand controlled cobalt catalyzed regiodivergent 1,2-hydroboration of 1,3-dienes” Sci. China Chem. 2019, 62, 336-340.

60. Yao, W.; Fang, H.; He, Q.; Peng, D.; Liu, G.; Huang, Z.* “A BEt3-Base Catalyst for Amide Reduction with Silane” J. Org. Chem. 2019, 84, 6084-6093.

59. Wen, H.; Wang, K.; Zhang, Y.; Liu, G.; Huang, Z.* “Cobalt-Catalyzed Regio- and Enantioselective Markovnikov 1,2-Hydrosilylation of Conjugated Dienes” ACS Catal. 2019, 9, 1612-1618.

58. Wen, H.; Liu, G.*; Huang, Z.* “Recent advances in tridentate iron and cobalt complexes for alkene and alkyne hydrofunctionalizations” Coord. Chem. Rev. 2019, 386, 138–153.

57. Tang, X.; Huang, Z.* "Transition-metal complex-catalyzed alkane functionalization" Chin. Sci. Bull. 2018, 63, 1348-1360

56. Peng, S.; Liu, G.*; Huang, Z.* “Mixed Diboration of Alkynes Catalyzed by LiOH: Regio- and Stereoselective Synthesis of cis-1,2-Diborylalkenes” Org. Lett. 2018, 20, 7363-7366.

55. Ma, X.; Qiao, L.; Liu, G.*; Huang, Z.* “A New Phosphine-Amine-Oxazoline Ligand for Ru-Catalyzed Asymmetric Hydrogenation of N-Phosphinylimines” Chin. J. Chem. 2018, 36, 1151-1155.

54. Tang, X.; Jia, X.; Huang, Z.* “Challenges and Opportunities for Alkane Functionalisation by Molecular Catalysts” Chem. Sci. 2018, 9, 288~299.

53. Zuo, Z.; Wen, H.; Liu, G.; Huang, Z.* “Cobalt-Catalyzed Hydroboration and Borylation of Alkenes and Alkynes” Synlett 2018, 29, 1421-1429.

52. Wen, H.; Wan, X.; Huang, Z.* "Asymmetric Synthesis of Silicon-Stereogenic Vinylhydrosilanes by Cobalt-Catalyzed Regio- and Enantioselective Alkyne Hydrosilylation with Dihydrosilanes" Angew. Chem. Int. Ed. 2018,57, 6319-6323.

51. Wang, Y.; Huang, Z.; Leng, X.; Zhu, H.; Liu, G.; Huang, Z.* “Transfer Hydrogenation of Alkenes Using Ethanol Catalyzed by A NCP Pincer Iridium Complex: Scope and Mechanism” J. Am. Chem. Soc. 2018, 140, 4417-4429.

50. Tang, X.; Jia, X.; Huang, Z.* “Thermal, Catalytic Conversion of Alkanes to Linear Aldehydes and Linear Amines” J. Am. Chem. Soc. 2018, 140, 4157-4163.

49. Fang, H.; He, Q.; Liu, G.; Huang, Z.* “Pincer Ruthenium Catalyzed Intramolecular Silylation of C(sp2)-H Bonds” Synlett. 2017, 28, 2468-2472.

48. Zhang, D.; Zhang, Y.; Hou, W.; Guan, Z.* Huang, Z.* “Phosphine-Iminoquinoline Iron Complexes for Ethylene Polymerization and Copolymerization” Organometallics. 2017, 36, 3758-3764.

47. Wen, H.; Zhang, L.; Zhu, S.; Liu, G.; Huang, Z.* “Stereoselective Synthesis of Trisubstituted Alkenes via Cobalt-Catalyzed Double Dehydrogenative Borylations of 1-Alkenes” ACS Catal. 2017, 7, 6419-6425.

46. Ma, X.; Zuo, Z.; Liu, G.; Huang, Z.* “Manganese-Catalyzed Asymmetric Hydrosilylation of Aryl Ketones” ACS Omega 2017, 2, 4688-4692.

45. Fang, H.; Hou, W.; Liu, G.; Huang, Z.* “Ruthenium-Catalyzed Site-Selective Intramolecular Silylation of Primary C–H Bonds for Synthesis of Sila-Heterocycles” J. Am. Chem. Soc. 2017, 139, 11601-11609.

44. Yang, Z.; Peng, D.; Du, X.; Huang, Z.*; Ma, S.* “Identifying a Cobalt Catalyst for Highly Selective Hydrosilylation of Allenes” Org. Chem. Front. 2017, 4, 1829.

43. Du, X.; Hou, W.; Zhang, Y.; Huang, Z.* “Pincer Cobalt Complex-Catalyzed Z-Selective Hydrosilylation of Terminal Alkynes” Org. Chem. Front. 2017, 4, 1517.

42. Du, X.; Huang, Z.* "Advances in Base-Metal-Catalyzed Alkene Hydrosilylation" ACS Catal. 2017, 7, 1227-1243.

41. Wang, Y.; Jia, X.; Qin, C.; Leng, X.; Huang, Z.* "An Agostic Iridium Pincer Complex as a Highly Efficient and Selective Catalyst for Monoisomerization of 1-Alkenes to trans-2-Alkenes" Angew. Chem. Int. Ed. 2017, 56, 1614-1618.

40. Fang, H.; Guo, L.; Zhan, Y.; Yao, W.; Huang, Z.* "A Pincer Ruthenium Complex for Regioselective C-H Silylation of Heteroarenes" Org. Lett. 2016,18, 5624-5627.

39. Zuo, Z.; Yang, J.; Huang, Z.* "Cobalt-Catalyzed Alkyne Hydrosilylation and Sequential Vinylsilane Hydroboration with Markovnikov Selectivity" Angew. Chem. Int. Ed. 2016, 55, 10839-10843.

38. Jia, X.; Qin, C.; Frieberger, T.; Guan, Z.*; Huang, Z.* "Efficient and Selective Degradation of Polyethylenes into Liquid Fuels and Waxes under Mild Conditions" Sci. Adv. 2016, 2, e1501591.

37. Yao, W.; Ma, X.; Guo, L.; Jia, X.; Hu. A.*; Huang, Z.* "A Highly Efficient Catalytic -Alkylation of Unactivated Amides Using Primary Alcohols" Tetrahedron Lett. 2016, 57, 2919-2921.

36. Du, X.; Zhang, Y.; Peng, D.; Huang, Z.* "Base Metal-Catalyzed Regiodivergent Alkene Hydrosilylations" Angew. Chem. Int. Ed. 2016, 55, 6671-6675.

35. Yao, W.; Fang, H.; Peng, S.; Wen, H.; Zhang, L.; Hu. A.*; Huang, Z.* "Cobalt- Catalyzed Borylation of Aryl Halides and Pseudohalides" Organometallics 2016, 35, 1559-1564.

34. Yao, W.; Jia, X.; Leng, X.; Goldman, A. S.; Brookhart, M.*; Huang, Z.* "Catalytic Alkane Transfer-Dehydrogenation by PSCOP Iridium Pincer Complexes" Polyhedron 2016, 116, 12-19.

33. Zuo, Z.; Huang, Z.* "Synthesis of 1,1-Diboronate Esters by Cobalt-Catalyzed Sequential Hydroboration of Terminal Alkynes" Org. Chem. Front. 2016, 3, 434-438.

32. Zhang, Y.; Fang, H.; Yao, W.; Leng, X.; Huang, Z.* "Synthesis of Pincer Hydrido Ruthenium Olefin Complexes for Catalytic Alkane Dehydrogenation" Organometallics 2016, 35, 181-188.

31. Jia, X.; Huang, Z.* "Conversion of Alkanes to Linear Alkylsilanes Using An Iridium-Iron-Catalysed Tandem Dehydrogenation-Isomerization-Hydrosilylation" Nat. Chem. 2016, 8, 157-161.

30. Zhang, L.; Huang, Z.* "Synthesis of 1,1,1-Tris(boronates) from Vinylarenes by Co-Catalyzed Dehydrogenative Borylations-Hydroboration" J. Am. Chem. Soc. 2015, 137, 15600-15603.

29. Peng, D.; Zhang, M.; Huang, Z.* "A General, Practical Triethylborane-Catalyzed Reduction of Carbonyl Functions to Alcohols" Chem. Eur. J. 2015, 21, 14737-14741.

28. Jia, X.; Huang, Z.* "Synthesis and Characterization of A Tetradentate PNCP Iridium Complex for Catalytic Alkane Dehydrogenation" Sci. China Chem. 2015, 58, 1340-1344

27. Zuo, Z.; Zhang, L.; Huang, Z.* "Iron-Catalyzed Asymmetric Hydrosilylation of Ketones" Chem. Commun. 2015, 51, 5073-5076

26. Zhang, Y.; Yao, W.; Fang, H.; Hu, A.*; Huang, Z.* "Catalytic Alkane Dehydrogenation" Sci. Bull. 2015, 60, 1316-1331.

25. Guo, L.; Ma, X.; Fang, H.; Jia, X.; Huang, Z.* “A General and Mild Catalytic ?-Alkylation of Unactivated Esters Using Alcohols” Angew. Chem. Int. Ed. 2015, 54, 4023-4027.

24. Zhang, L.;# Zuo, Z.;# Wang, X.; Huang, Z.* "Cobalt-Catalyzed Enantioselective Hydroboration of 1,1,-Disubstituted Aryl Alkenes" J. Am. Chem. Soc. 2014, 136, 15501-15504. (# contributed equally)

23. Cao, Y.; Zhang, Y.; Zhang, L.; Zhang, D; Leng, X.; Huang, Z.* "Selective Synthesis of Secondary Benzylic (Z)-Allylboronates by Fe-Catalyzed 1,4-Hydroboration of 1-Aryl-Substituted 1,3-Dienes" Org. Chem. Front. 2014, 1, 1101-1106.

22. Jia, X.; Qin, C.; Leng, X.; Huang, Z.* "Iridium Complexes of New PCN Pincer Ligands: Catalytic Alkane Dehydrogenation and Alkene Isomerization" Chem. Commun. 2014, 50, 11056-11059.

21. Zhang, Y.; Cao, Y.; Leng, X.; Chen, C.*; Huang, Z.* "Cationic Palladium (II) Complexes of Phosphine-Sulfonamide Ligands: Synthesis, Characterization, and Catalytic Ethylene Oligomerization" Organometallics 2014, 33, 3738-3745.

20. Zhang, L.; Zuo, Z.; Leng, X.; Huang, Z.* "A Cobalt-Catalyzed Alkene Hydroboration with Pinacolborane" Angew. Chem. Int. Ed. 2014, 53, 2696-2700.

19. Yao, W.; Zhang, Y.; Jia, X.; Huang, Z.* "Selective Catalytic Transfer Dehydrogenation of Alkanes and Heterocycles by an Iridium Complex" Angew. Chem. Int. Ed. 2014, 53, 1390-1394.

18. Peng, D.; Zhang, Y.; Du, X.; Zhang, L.; Leng, X.; Walter, M. D.*; Huang, Z.* "Phosphinite-Iminopyridine Iron Catalysts for Chemoselective Alkene Hydrosilylation" J. Am. Chem. Soc. 2013, 135, 19154-19166.

17. Zhang, L.; Huang, Z.* "Iron-Catalyzed Alkene Hydroboration with Pinacolborane" Synlett 2013, 24, 1745-1747.

16. Guo, L.; Liu, Y.; Yao, W.; Leng, X.; Huang, Z.* "Iridium-Catalyzed Selective -Alkylation of Unactivated Amides with Primary Alcohols" Org. Lett. 2013, 15, 1144-1147.

15. Zhang, L.; Peng, D.; Leng, X.; Huang, Z.* "Iron-Catalyzed, Atom-Economical, Chemo- and Regioselective Alkene Hydroboration with Pinacolborane" Angew. Chem. Int. Ed. 2013, 52, 3676-3680.

Before SIOC:

14. Biswas, S.; Huang, Z.; Choliy, Y.; Wang, D. Y.; Brookhart, M.;* Krogh-Jespersen, K.;* Goldman, A. S.* "Olefin isomerization by Iridium Pincer Catalysts. Experimental Evidence for an Allyl Pathway and an Unconventional Mechanism Predicted by DFT Calculations". J. Am. Chem. Soc. 2012, 134, 13276-13295.

13. Huang, Z.; Hartwig, J. F.* "Copper(I) Enolate Complexes in ?-Arylation Reactions: Synthesis, Reactivity, and Mechanism" Angew. Chem. Int. Ed. 2012, 51, 1028-1032.

12. Vicente, B. C.; Huang, Z.; Brookhart, M.;* Goldman, A. S.;* Scott, S. L.; "Reactions of Phosphinites with Oxide Surfaces: A New Method for Anchoring Organic and Organometallic Complexes" Dalton Trans. 2011, 40, 4268-4274.

11. Huang, Z.; Zhou, J. R.; Hartwig, J. F.* "N-H Activation of Hydrazines by Iridium(I). Double N-H Activation to Form Iridium Aminonitrene Complexes" J. Am. Chem. Soc. 2010, 132, 11458-11460.

10. Huang, Z.; White, P. S.; Brookhart, M.* "Ligand Exchanges and Selective Catalytic Hydrogenation in Molecular Single Crystals" Nature 2010, 465, 598-601.

9. Huang, Z.; Rolfe, E.; Carson, E. C.; Brookhart, M.;* Goldman, A. S.;* El-Khalafy, S. H.; MacArthur, A. H. R. "Efficient Heterogeneous Dual Catalyst Systems for Alkane Metathesis" Adv. Synth. & Catal. 2010, 352, 125-135.

8. Huang, Z.; Brookhart, M.;* Goldman, A. S.;* Kundu, S.; Ray, A.; Scott, S. L.; Vicente, B. C. "Highly Active and Recyclable Heterogeneous Iridium Pincer Catalysts for Transfer Dehydrogenation of Alkanes" Adv. Synth. & Catal. 2009, 351, 188-206.

7. Bailey, B. C.; Schrock, R. R.;* Kundu, S.; Goldman, A. S.; Huang, Z.; Brookhart, M. "Evaluation of Molybdenum and Tungsten Metathesis Catalysts for Homogeneous Tandem Alkane Metathesis" Organometallics 2009, 28, 355-360.

6. Goldman, A. S.;* Roy, A. H.; Huang, Z.; Ahuja, R.; Schinski, W.; Brookhart, M.* "Catalytic Alkane Metathesis by Tandem Alkane Dehydrogenation Olefin Metathesis" Science 2006, 312, 257-261.

5. Zou, R. Q.; Liu, C. S.; Huang, Z.; Hu, T. L.; Bu, X. H.* "Syntheses, Structure, and Properties of the Metal Complexes with 3-(2-pyridyl)pyrazole-based Ligands: Tuning the Complex Structures by Ligand modifications" Crystal Growth & Design 2006, 6, 99-108.

4. Huang, Z.; Tian, J. L.; Bu, X. H.* "Self-assembly of Novel Discrete Binuclear Molecular Box Structure from a Novel bis-N,O-bidentate Schiff-base Ligand and Zn(II), Co(II) Salts" Inorg. Chem. Commum. 2005, 8, 194-198.

3. Huang, Z.; Song, H. B.; Du, M.; Chen, S. T.; Bu, X. H.;* Ribas, J. "Coordination Polymers Assembled from Angular Dipyridyl Ligands and Cu(II), Cd(II), Co(II) Salts: Crystal Structures and Properties" Inorg. Chem. 2004, 43, 931-944.

2. Huang, Z.; Du, M.; Song, H. B.; Bu, X. H.* "Effect of Anions on the Framework Formation of Novel Ag(I) Coordination Polymers with Angular Bridging Ligands" Crystal Growth & Design 2004, 4, 71-78.

1. Du, M.; Bu, X. H.;* Huang, Z.; Chen, S. T.; Guo, Y. M.; Diaz, C.; Ribas, J. "From Metallacyclophanes to 1-D Coordination Polymers: Role of Anions in Self-Assembly Processes of Copper(II) and 2,5-bis(3-pyridyl)-1,3,4-oxadiazole" Inorg. Chem. 2003, 42, 552-559.



2.   Brookhart, M.; Goldman, A.; Carson, E.; Huang, Z.; Kundu, S. K. " Supported Iridium Catalysts" US 8,362,312 B2.
1.   Goldman, A. S.; Brookhart, M.; Roy, A. H.; Ahuja, R.; Huang. Z. " Dual Catalyst System for Alkane Metathesis "US 7,902,417 B2.